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Its byproduct of the catalytic converter which converts carbon monoxide to H2O which is water.
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Like said don't over tighten. Exhaust flanges are only 30-40 ft/lbs. very light. Now that they are over tightened theyre done. Only fix is thicker gaskets or what I do which was said already is use RTV copper silicone. The stuff works so well lots don't even use gaskets! They just use the silicone and make a gasket.
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