Paint removal advice needed
 

How do I get rid of this safely (see pics)? Also, does this type of carelessness indicate a possible bigger cosmetic issue? I bought the car used about two months ago but carfax didn't indicate any incidents. I'm also now starting to worry because after a few weeks I started noticing that my front bumper isn't aligned like it should be. I know it's kind of too late to make a stink about it, but just need advice on how to get her looking nice again.

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tape up around the windows and use paint remover. Don't think it will hurt the windows or the rubber around it. And yeah, I'd be worried.