any wax or sealant also know as a LSP usually needs at least 12 hours to cure... some of them need up to 24 hours to completely cure.
As for the water spots on the window... you can use white vinegar and distilled water mixed and that will sometimes take them off, i'm not quite sure of the ratio though so try a search on google.
You can use a mild pollish on the windows as well to get them out. I will use my final polish with white pad sometimes to remove any kind of water spots that might have gotten left on the car.
Be sure once you get them off, try to keep them off with rain-x or some other type of glass sealant. Some people also use a quick deailer on their windows.
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